Electrochemistry and Solid-State Letters, 11 (6),H160-H164(2008).

Novel FTO/ SnO2/BiVO4 composite photo-electrode for water oxidation under visible light irradiation

Ponchio Chatchai, Yoshinori Murakami, Shin-ya Kishioka, Atsuko Y. Nosaka, and Yoshio Nosaka

Abstract
An SnO2 layer prepared from ethanol solution was applied to fabricate an FTO/SnO2/BiVO4 composite photo-electrode. The layered composite films were characterized by XRD, SEM and XPS techniques. The photocurrent efficiency of BiVO4 increased remarkably when an SnO2 film was layered between the BiVO4 layer and the FTO conducting electrode, indicating the efficient charge separation via the electron transfer from to SnO2 and the blocking of the hole transfer from BiVO4 to the FTO surface. It was also demonstrated that the sequence for depositing the individual metal oxide layer on the FTO substrate was an important factor for such efficient charge separation of electrode.

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